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The Buildup Breakdown: How Minerals and Metals Impact Hair

By Nutrafol Team2025-12-04

When you think about hair buildup, your mind might go straight to leftover conditioner or dry shampoo. But buildup isn’t just product residue. Several additional factors can impact hair, originating from the body, like natural oils, as well as the environment, like air pollution, and even minerals or metals from shower water.1,2 

Shower water is an environmental exposure our hair has to deal with regularly. Hard water has a high concentration of dissolved minerals—primarily calcium and magnesium. It forms when groundwater passes through limestone or chalk, picking up minerals and sometimes even trace metals, like iron or copper. Hard water is a problem in over 85% of the United States, which means most of us are exposed daily.3

You can spot hard water in your home if you notice a slimy film on your hands after washing, cloudy glassware, or a white, crusty buildup on your showerhead. If you’re unsure, the EWG Tapwater database is a good resource to check by zip code. If you want precise details about your home specifically, some cities and companies provide water testing.

How hard water affects your hair.

The outer layer of your hair (called the cuticle) is made of a protein called keratin that’s held together by chemical bonds. When your hair gets wet, those bonds loosen slightly, which lifts the cuticle, so water (along with whatever’s in it) can seep in. That’s when minerals and metals in the water can attach themselves to your hair fibers, leading to breakage and more fragile hair over time.4,5

If your hair is colored, bleached, or chemically treated, it’s even more vulnerable because these chemical processes make it easier for minerals and metals to enter and bind to hair strands.6

How buildup affects hair quality.

Over time, mineral and metal buildup doesn’t just coat your hair; it can change its structure.

Studies show that hair exposed to hard water tends to have a rougher surface, reduced thickness, and lower tensile strength, meaning it can break more easily.4,6 This causes hair that feels dull, dry, or tangly—no matter what conditioner you use.

And it’s not just calcium and magnesium that can damage hair. Heavy metals like iron, copper, lead, or cadmium (a metal found in both water and air pollution) can cause similar problems.1,2 These metals can dull color-treated hair and make strands feel more coarse.7

Air pollution, like from car exhaust or industrial facilities, adds another layer of complexity. Tiny airborne particles can stick to sebum (the natural oil on your scalp and hair), worsening buildup and further dulling your shine.8

It’s important to remember: while chemically treated hair is more vulnerable, undyed hair isn’t immune.9 Hard water and environmental exposure can eventually affect any type of hair.

Solutions for mineral and metal buildup.

There’s no need to worry if you find out you have hard water in your home. Thankfully, there are ways to help protect your hair from the damage caused by hard water and help restore its health.

1. Water treatments

If your area has hard water, consider these home water treatments:

  • Ion exchange water softener: These systems replace calcium and magnesium in the water with sodium or potassium.3

  • Reverse osmosis: Uses very high pressure and specialized membranes to remove both heavy metals and hard minerals from your water.3

  • Shower filters: A lower cost- and resource-intensive option than whole-house systems; but read the fine print. Most standard shower filters (those with NSF/ANSI 177 or NSF/ANSI 42 certification) only remove chlorine, not minerals or metals. Some newer brands include additional filtration media designed to capture heavy metals, microplastics, and other contaminants. It’s always best if you can verify the company’s lab data and ensure they have independent testing to support their claims. Shower filters need regular replacement, typically every 3–6 months, to remain effective. Check your shower filter manufacturer to see how often they recommend replacing your filter.

2. Cleansing treatments.

Even with the best water treatments, it’s important to use products that will cleanse your scalp—from water, air pollution, and other buildup—while supporting the scalp’s microbiome. 

  • Everyday shampoos contain mild sequestering agents, chemicals that bind to metals to prevent soap scum from forming on the hair and scalp in the presence of hard water.10

  • Chelating shampoos go a step further. They use stronger agents like EDTA or citric acid to actually bind and remove mineral deposits.11 Think of them as a deep cleanse for your hair. These should be used sparingly (once every week or two) because overuse can dry out the hair.

  • Clarifying shampoos, by contrast, target product buildup, not minerals or metals.10 They can be useful but won’t necessarily tackle hard water effects.

  • Apple cider vinegar (ACV): Rinsing with ACV can dissolve mineral particles and smooth the cuticle, restoring shine.9,12 ACV has a low pH (around 3.5), and its acidity can also help rebalance the scalp’s pH and “seal” the hair shaft, essentially counteracting the effects of hard water. Just dilute it before use (1–2 tablespoons in a cup of water), and use before shampooing and conditioning 1–2 times weekly.

The bottom line.

Mineral and metal exposure through hard water is an incredibly common issue affecting not just the look of your hair, but also its health—in some cases, leaving it rough, dull, and prone to breakage. If you’ve noticed any of these changes in your hair, mineral or metal buildup could be part of the reason. 

There are ways to lessen your exposure to minerals and metals from hard water. By combining water treatments or filtration with a consistent hair care routine that includes cleansing shampoos or ACV rinses, you can help minimize metal buildup for smoother, stronger, healthier hair.

1. Tubia C, Fernández-Botello A, Dupont J, Gómez E, Desroches J, Attia J, Loing E. A New Ex Vivo Model to Evaluate the Hair Protective Effect of a Biomimetic Exopolysaccharide against Water Pollution. Cosmetics. 2020;7(4):78. https://doi.org/10.3390/cosmetics7040078

2. Galliano A, Ye C, Su F, et al. Particulate matter adheres to human hair exposed to severe aerial pollution: consequences for certain hair surface properties. Int J Cosmet Sci. 2017;39(6):610–616. doi:10.1111/ics.12416 https://doi.org/10.1111/ics.12416

3. Heidekamp A, Lemley A. Water Bulletin: Hard Water. 2005. https://www.stlawco.gov/sites/default/files/PublicHealth/Hard%20Water%20Iron.pdf

4. Luqman MW, Ramzan MH, Javaid U, Ali R, Shoaib M, Luqman MA. To Evaluate and Compare Changes in Baseline Strength of Hairs after Treating them with Deionized Water and Hard Water and its Role in Hair Breakage. Int J Trichology. 2018;10(3):113–117. https://doi.org/10.4103/ijt.ijt_115_16

5. Evans AO, Marsh JM, Wickett RR. The structural implications of water hardness metal uptake by human hair. Int J Cosmet Sci. 2011;33(5):477–482. https://doi.org/10.1111/j.1468-2494.2011.00659.x

6. Srinivasan G,Rangachari SC. Scanning electron microscopy of hair treated in hard water. Int J Dermatol. 2016;55:e344–e346. https://doi.org/10.1111/ijd.13141

7. Shim JY, Lee HS, Shin WJ, et al. The effects of dyes and bleaches on the sorption and desorption of trace elements in human hair. Environ Geochem Health. 2023;45(5):2349–2358. https://doi.org/10.1007/s10653-022-01358-x

8. Punyani S, et al. The Impact of Shampoo Wash Frequency on Scalp and Hair Conditions.Skin Appendage Disord. 2021;7(3):183–193. https://doi.org/10.1159/000512786

9. Zhang D, Baghdadli N, Greaves AJ. Reinforcing chemically treated human hair with citric acid. Int J Cosmet Sci. 2025;47:411–423. https://doi.org/10.1111/ics.13039

10. Draelos ZD. Essentials of Hair Care Often Neglected: Hair Cleansing. Int J Trichology. 2010;2(1):24–29. doi:10.4103/0974-7753.66909 https://pmc.ncbi.nlm.nih.gov/articles/PMC3002407/

11. Hodes J, Sielaff P, Metz H, Kessler-Becker D, Gassenmeier T, Neubert RHH. The role of chelating agents and amino acids in preventing free radical formation in bleaching systems. Free Radical Biology and Medicine. 2018;129:194–201. https://doi.org/10.1016/j.freeradbiomed.2018.09.023

12. Ousaaid D, Laaroussi H, Mechchate H, et al. The Nutritional and Antioxidant Potential of Artisanal and Industrial Apple Vinegars and Their Ability to Inhibit Key Enzymes Related to Type 2 Diabetes In Vitro. Molecules. 2022;27(2):567. Published 2022 Jan 17. https://doi.org/10.3390/molecules27020567

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